Net-SMS is a very simple and easy to use application which can be used from Windows Platform. This is a very small application and is java based.
All you need is to register at Way2SMS.com (the registration is free) and get a username and password for yourself. The application uses Rich Address Book features. Moreover you can import your contacts from Yahoo, Google or Outlook Address book.
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How to install Windows XP in pre-installed Vista
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How to install Windows XP in pre-installed Vista